Study: Water vapor may help 'flatten global warming trend'

By Doyle Rice, USA TODAY
www.usatoday.com

Why the Earth's surface temperature hasn't warmed as expected over the past decade continues to be a puzzle for scientists. One study out earlier this month theorized that the Earth's climate may be less sensitive to greenhouse gases than currently assumed.

Another surprising factor could be the amount of water vapor way up in the stratosphere, according to a new study out Thursday in the journal Science.

Water vapor, a potent, natural greenhouse gas that absorbs sunlight and re-emits heat, is "a wild card" of global warming, says the paper's lead author, senior scientist Susan Solomon of the National Oceanic and Atmospheric Administration in Boulder, Colo. Solomon was also a co-chair of one of the groups within the Intergovernmental Panel on Climate Change that put out the definitive forecast of global warming in 2007.

In the Science paper, Solomon and her colleagues found that a drop in the concentration of water vapor in the stratosphere "very likely made substantial contributions to the flattening of the global warming trend since about 2000."

While climate warming is continuing — the decade of 2000 to 2009 was the hottest on record worldwide — the increase in temperatures was not as rapid as in the 1990s.

The stratosphere is the layer of the atmosphere just above the troposphere, which is the layer of air here at the planet's surface. (The troposphere goes from the surface up to about 8 miles, and the stratosphere is from about 8 to 30 miles above the surface.)

The decline in water vapor in the stratosphere slowed the rate of surface warming by about 25%, compared to that which would have occurred due to carbon dioxide and other greenhouse gases, notes the study. Specifically, the planet should have warmed 0.25 degree F during the 2000s, but because of the influence of the water vapor, it rose just 0.18 degree F.

"We call this the 10/10/10 paper," says Solomon. "10 miles above your head, there is 10% less water vapor than there was 10 years ago."

Why did the water vapor decrease? "We really don't know," says Solomon, "We don't have enough information yet."

The findings are "surprising," says Bill Randel, an atmospheric chemist at the National Center for Atmospheric Research, who was not part of the study. He said it was surprising how big an effect such a very little change in stratospheric water vapor has had on the surface climate.

These fluctuations in water vapor could be part of a feedback loop. Although it's known that water vapor in the troposphere increases as the climate warms — and is a major climate feedback that is well simulated in global climate models — in sharp contrast, models do a poor job of simulating water vapor in the stratosphere, according to the paper.

But Solomon points out this isn't an indication that predictions on global warming are overstated: "This doesn't mean there isn't global warming," notes Solomon. "There's no significant debate that it is warmer now than it was 100 years ago, due to anthropogenic (man-made) greenhouse gases."

And how will this water vapor affect future global warming? "We really don't know the answer to this," says Solomon. "If the water changes are due to the specific way the sea-surface temperature pattern looks right now, then it may well not be linked to the overall warming. It could just be a source of variability from one decade to another as the ocean pattern slowly changes. Or it could be linked to the overall warming of the tropics, in which case it could continue to 'put the brakes on.' Only time will tell, and more data."

Cyclonic spray scrubber

Cyclonic spray scrubbers are an air pollution control technology. They use the features of both the dry cyclone and the spray chamber to remove pollutants from gas streams.

Generally, the inlet gas enters the chamber tangentially, swirls through the chamber in a corkscrew motion, and exits. At the same time, liquid is sprayed inside the chamber. As the gas swirls around the chamber, pollutants are removed when they impact on liquid droplets, are thrown to the walls, and washed back down and out.

Cyclonic scrubbers are generally low- to medium-energy devices, with pressure drops of 4 to 25 cm (1.5 to 10 in) of water. Commercially available designs include the irrigated cyclone scrubber and the cyclonic spray scrubber.

In the irrigated cyclone (Figure 1), the inlet gas enters near the top of the scrubber into the water sprays. The gas is forced to swirl downward, then change directions, and return upward in a tighter spiral. The liquid droplets produced capture the pollutants, are eventually thrown to the side walls, and carried out of the collector. The "cleaned" gas leaves through the top of the chamber.

The cyclonic spray scrubber (Figure 2) forces the inlet gas up through the chamber from a bottom tangential entry. Liquid sprayed from nozzles on a center post (manifold) is directed toward the chamber walls and through the swirling gas. As in the irrigated cyclone, liquid captures the pollutant, is forced to the walls, and washes out. The "cleaned" gas continues upward, exiting through the straightening vanes at the top of the chamber.

This type of technology is a part of the group of air pollution controls collectively referred to as wet scrubbers.

Particulate collection



Cyclonic spray scrubbers are more efficient than spray towers, but not as efficient as venturi scrubbers, in removing particulate from the inlet gas stream. Particulates larger than 5 µm are generally collected by impaction with 90% efficiency. In a simple spray tower, the velocity of the particulates in the gas stream is low: 0.6 to 1.5 m/s (2 to 5 ft/s).

By introducing the inlet gas tangentially into the spray chamber, the cyclonic scrubber increases gas velocities (thus, particulate velocities) to approximately 60 to 180 m/s (200 to 600 ft/s). The velocity of the liquid spray is approximately the same in both devices. This higher particulate-to-liquid relative velocity increases particulate collection efficiency for this device over that of the spray chamber. Gas velocities of 60 to 180 m/s are equivalent to those encountered in a venturi scrubber.

However, cyclonic spray scrubbers are not as efficient as venturi scrubbers because they are not capable of producing the same degree of useful turbulence.
Gas collection

High gas velocities through these devices reduce the gas-liquid contact time, thus reducing absorption efficiency. Cyclonic spray scrubbers are capable of effectively removing some gases; however, they are rarely chosen when gaseous pollutant removal is the only concern.

Maintenance problems

The main maintenance problems with cyclonic scrubbers are nozzle plugging and corrosion or erosion of the side walls of the cyclone body. Nozzles have a tendency to plug from particulates that are in the recycled liquid and/or particulates that are in the gas stream. The best solution is to install the nozzles so that they are easily accessible for cleaning or removal.

Due to high gas velocities, erosion of the side walls of the cyclone can also be a problem. Abrasion-resistant materials may be used to protect the cyclone body, especially at the inlet.

From http://en.wikipedia.org/

Cyclonic separation

Cyclonic separation is a method of removing particulates from an air, gas or water stream, without the use of filters, through vortex separation. Rotational effects and gravity are used to separate mixtures of solids and fluids.

A high speed rotating (air)flow is established within a cylindrical or conical container called a cyclone. Air flows in a spiral pattern, beginning at the top (wide end) of the cyclone and ending at the bottom (narrow) end before exiting the cyclone in a straight stream through the center of the cyclone and out the top. Larger (denser) particles in the rotating stream have too much inertia to follow the tight curve of the stream and strike the outside wall, falling then to the bottom of the cyclone where they can be removed. In a conical system, as the rotating flow moves towards the narrow end of the cyclone the rotational radius of the stream is reduced, separating smaller and smaller particles. The cyclone geometry, together with flow rate, defines the cut point of the cyclone. This is the size of particle that will be removed from the stream with a 50% efficiency. Particles larger than the cut point will be removed with a greater efficiency, and smaller particles with a lower efficiency.

An alternative cyclone design uses a secondary air flow within the cyclone to keep the collected particles from striking the walls to protect them from abrasion. The primary air containing the particulate enters from the bottom of the cyclone and is forced into spiral rotation by a stationary spinner. The secondary air flow enters from the top of the cyclone and moves downward toward the bottom, intercepting the particulate from the primary air. The secondary air flow also allows the collector to be mounted horizontally because it pushes the particulate toward the collection area.

Large scale cyclones are used in sawmills to remove sawdust from extracted air. Cyclones are also used in oil refineries to separate oils and gases, and in the cement industry as components of kiln preheaters. Smaller cyclones are used to separate airborne particles for analysis. Some are small enough to be worn clipped to clothing and are used to separate respirable particles for later analysis.

Analogous devices for separating particles or solids from liquids are called hydrocyclones or hydroclones. These may be used to separate solid waste from water in wastewater and sewage treatment.

From http://en.wikipedia.org/

Biofilter

Biofiltration is a pollution control technique using living material to capture and biologically degrade process pollutants. Common uses include processing waste water, capturing harmful chemicals or silt from surface runoff, and microbiotic oxidation of contaminants in air.



Examples of biofiltration include;

* Bioswales, Biostrips, Biobags, Bioscrubbers, and Trickling filters
* Constructed wetlands and Natural wetlands
* Slow sand filters
* Treatment ponds
* Green belts
* Living walls
* Riparian zones, Riparian forests, Bosques



Control of air pollution

When applied to air filtration and purification, biofilters use microorganisms to remove air pollution. The air flows through a packed bed and the pollutant transfers into a thin biofilm on the surface of the packing material. Microorganisms, including bacteria and fungi are immobilized in the biofilm and degrade the pollutant. Trickling filters and bioscrubbers rely on a biofilm and the bacterial action in their recirculating waters.

The technology finds greatest application in treating malodorous compounds and water-soluble volatile organic compounds (VOCs). Industries employing the technology include food and animal products, off-gas from wastewater treatment facilities, pharmaceuticals, wood products manufacturing, paint and coatings application and manufacturing and resin manufacturing and application, etc. Compounds treated are typically mixed VOCs and various sulfur compounds, including hydrogen sulfide. Very large airflows may be treated and although a large area (footprint) has typically been required -- a large biofilter (>200,000 acfm) may occupy as much or more land than a football field -- this has been one of the principal drawbacks of the technology. Engineered biofilters, designed and built since the early 1990s, have provided significant footprint reductions over the conventional flat-bed, organic media type.



One of the main challenges to optimum biofilter operation is maintaining proper moisture throughout the system. The air is normally humidified before it enters the bed with a watering (spray) system, humidification chamber, bioscrubber, or biotrickling filter. Properly maintained, a natural, organic packing media like peat, vegetable mulch, bark or wood chips may last for several years but engineered, combined natural organic and synthetic component packing materials will generally last much longer, up to 10 years. A number of companies offer these types or proprietary packing materials and multi-year guarantees, not usually provided with a conventional compost or wood chip bed biofilter.

Although widely employed, the scientific community is still unsure of the physical phenomena underpinning biofilter operation, and information about the microorganisms involved continues to be developed. A biofilter/bio-oxidation system is a fairly simple device to construct and operate and offers a cost-effective solution provided the pollutant is biodegradable within a moderate time frame (increasing residence time = increased size and capital costs), at reasonable concentrations (and lb/hr loading rates) and that the airstream is at an organism-viable temperature. For large volumes of air, a biofilter may be the only cost-effective solution. There is no secondary pollution (unlike the case of incineration where additional CO2 and NOx are produced from burning fuels) and degradation products form additional biomass, carbon dioxide and water. Media irrigation water, although many systems recycle part of it to reduce operating costs, has a moderately high biochemical oxygen demand (BOD) and may require treatment before disposal. However, this "blowdown water", necessary for proper maintenance of any bio-oxidation system, is generally accepted by municipal POTWs without any pretreatment.

Biofilters are being utilized in Columbia Falls, Montana at Plum Creek Timber Company's fiberboard plant. The biofilters decrease the pollution emitted by the manufacturing process and the exhaust emitted is 98% clean. The newest, and largest, biofilter addition to Plum Creek cost $9.5 million, yet even though this new technology is expensive, in the long run it will cost less overtime than the alternative exhaust-cleaning incinerators fueled by natural gas (which are not as environmentally friendly). The biofilters use trillions of microscopic bacteria that cleanse the air being released from the plant.

Water treatment



Trickling filters have been used to filter water for various end uses for almost two centuries. Biological treatment has been used in Europe to filter surface water for drinking purposes since the early 1900s and is now receiving more interest worldwide. Biological treatment methods are also common in wastewater treatment, aquaculture and greywater recycling as a way to minimize water replacement while increasing water quality.

For drinking water, biological water treatment involves the use of naturally occurring micro-organisms in the surface water to improve water quality. Under optimum conditions, including relatively low turbidity and high oxygen content, the organisms break down material in the water and thus improve water quality. Slow sand filters or carbon filters are used to provide a place on which these micro-organisms grow. These biological treatment systems effectively reduce water-borne diseases, dissolved organic carbon, turbidity and colour in surface water, improving overall water quality.

Use in aquaculture



The use of biofilters are commonly used on closed aquaculture systems, such as recirculating aquaculture systems (RAS). Many designs are used, with different benefits and drawbacks, however the function is the same: reducing water exchanges by converting ammonia to nitrate. Ammonia (NH4+ and NH3) originates from the brachial excretion from the gills of aquatic animals and from the decomposition of organic matter. As ammonia-N is highly toxic, this is converted to a less toxic form of nitrite (by Nitrosomonas sp.) and then to an even less toxic form of nitrate (by Nitrobacter sp.). This "nitrification" process requires oxygen (aerobic conditions), without which the biofilter can crash. Furthermore, as this nitrification cycle produces H+, the pH can decrease which necessitates the use of buffers such as lime.

From http://en.wikipedia.org/